Standard Thermometer
The peculiarities in the construction of thermometers will be best understood by describing the manufacture of a Standard Thermometer, which is one of the most accurate make, and the scale of which is divided independently of any comparison with another thermometer. Fig. 36 is an illustration of such an instrument, on a silvered brass scale.
Selection
The bulb is never blown by the breath, but by an elastic caoutchouc ball containing air, so that the introduction of moisture is avoided. The spherical form is to be preferred; for it is best adapted to resist the varying pressure of the atmosphere. The bulbs should not be too large, or the mercury will take some time to indicate sudden changes of temperature. Cylindrical bulbs are sometimes desirable, as they offer larger surfaces to the mercury, and enable thermometers to be made more sensitive.
The mercury, with which the bulb is to be filled, should be quite pure, and freed from moisture and air by recent boiling.
Filling the Tube.—The filling is effected by heating the bulb with the flame of a spirit-lamp, while the open end is embedded in mercury. Upon allowing the bulb to cool, the atmospheric pressure drives some mercury into it; and the process of heating and cooling is thus continued until sufficient mercury is introduced. The mercury is next boiled in the tube, to expel any air or moisture that may be present. In order to close the tube and exclude all air, the artist ascertains that the tube contains the requisite quantity of mercury; then, by holding the bulb over the spirit flame, he causes the mercury to fill the whole of the tube, and dexterously removing it from the source of heat, he, at the same instant, closes it with the flame of a blow-pipe. If any air remain in the tube, it is easily detected; for if the instrument be inverted, the mercury will fall to the extremity of the tube, if there is a perfect vacuum, unless the tube be so finely capillary that its attraction for the mercury is sufficient to overcome the force of gravity, in which case the mercury will retain its position in every situation of the instrument. If, however, the mercury fall and does not reach quite to the extremity of the bore, some air is present, which must be removed.
The Graduation.—The thermometer is now prepared for graduation, the first part of which process is the determination of two fixed points. These are given by the temperatures of melting ice and of the vapour of boiling water. Melting ice has always the same temperature in every place and under all circumstances; provided only that the water from which the ice is congealed is free from salts. The temperature of the vapour of boiling water depends upon the pressure of the atmosphere, but is always constant for the same pressure.
The fixed point corresponding to the temperature of melting ice is called the freezing point. It is obtained by keeping the bulb and the part of the tube occupied by mercury immersed in melting ice, until the mercury contracts to a certain point, where it remains stationary. This position of the end of the mercury is then marked upon the tube.
The boiling point is not so easily determined, for the barometer must be consulted about the same time. The boiling apparatus is generally constructed of copper. It consists of a cylindrical boiler, heated from the base by a spirit lamp or charcoal fire. An open tube two or three inches in diameter and of suitable length enters the top of the boiler. This tube is enveloped by another fixed to the top of the boiler but not opening into it, and so that the two tubes are about an inch apart. The object of the outer tube is to protect the inner tube from the cold temperature of the air. The outer tube has an opening at the top for the admission of the thermometer, and a hole near the bottom for the escape of steam through a spout. When the water is made to boil, the steam rises in the inner tube, fills the space between the tubes, and escapes at the spout. The thermometer is then passed down into the inner cylinder, and held securely from the top by means of a piece of caoutchouc. The tubes or cylinders should be of sufficient length to prevent the thermometer entering the water. This is necessary because the temperature of boiling water is influenced by any substance which it holds in chemical solution; and, moreover, its temperature increases with the depth, owing to the pressure of the upper stratum. The thermometer being thus surrounded with steam, the mercury rises in the tube. As it does so, the tube should be depressed so as always to keep the top of the mercury just perceptible. When the temperature of the vapour is attained, the mercury ceases to rise, and remains stationary. The position of the end of the mercury is now marked upon the tube, and the “boiling-point” is obtained.
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